Chlorine dioxide as a disinfectant

description of chlorine dioxide as a disinfectant

Source: Chlorine dioxide as a disinfectant

Chlorine dioxide is mainly used as a bleach. As a disinfectant it is effective even at low concentrations, because of its unique qualities.

Figure 1: sir Humphrey Day discovered chlorine dioxide in 1814.

When was chlorine dioxide discovered?
Chlorine dioxide was discovered in 1814 by Sir Humphrey Davy. He produced the gas by pouring sulphuric acid (H2SO3) on potassium chlorate (KClO3). Than he replaced sulphuric acid by hypochlorous acid (HOCl). In the last few years this reaction has also been used to produce large quantities of chlorine dioxide. Sodium chlorate (NaClO3) was used instead of potassium chlorate.
2NaClO3 + 4HCl ® 2ClO2 + Cl2 + 2NaCl + 2H2O

What are the characteristics of chlorine dioxide ?
Chlorine dioxide (ClO2) is a synthetic, green-yellowish gas with a chlorine-like, irritating odor. Chlorine dioxide is a neutral chlorine compound. Chlorine dioxide is very different from elementary chlorine, both in its chemical structure as in its behavior. Chlorine dioxide is a small, volatile and very strong molecule. In diluted, watery solutions chlorine dioxide is a free radical. At high concentrations it reacts strongly with reducing agents. Chlorine dioxide is an unstable gas that dissociates into chlorine gas (Cl2), oxygen gas (O2) and heat. When chlorine dioxide is photo-oxidized by sunlight, it falls apart. The end-products of chlorine dioxide reactions are chloride (Cl-), chlorite (ClO-) and chlorate (ClO3-).

At –59°C, solid chlorine dioxide becomes a reddish liquid. At 11°C chlorine dioxide turns into gas.
Chlorine dioxide is 2,4 times denser than air. As a liquid chlorine dioxide has a bigger density than water.

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